van’t Hoff factor (i = ratio of actual particle effect to ideal nonelectrolyte; for full dissociation of NaCl)

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i = ratio of actual particle effect to ideal nonelectrolyte; for full dissociation of NaCl i→2, CaCl₂ i→3 (ideal)

What each symbol means

SymbolWhat it stands for
ivan’t Hoff factor
expectedSame formula with i=1 for formula unit as single particle
observedMeasured ΔT_b, ΔT_f, π, etc.

When to use this

Defined relative to ideal nonelectrolyte baseline; accounts for dissociation/association.