Hydration enthalpy of Group 1 cations (Magnitude of hydration enthalpy (exothermic) decreases down Group 1: Li⁺ is most heavily)

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Magnitude of hydration enthalpy (exothermic) decreases down Group 1: Li⁺ is most heavily hydrated.

What each symbol means

SymbolWhat it stands for
ΔH_hydEnthalpy change when gaseous ion is hydrated

When to use this

Smaller ions bind water dipoles more strongly; Li⁺ has largest |ΔH_hyd|.