Chelate effect and overall stability constant (β) (Chelating ligands replace multiple monodentates: entropy gain (more particles) drives)
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Chelating ligands replace multiple monodentates — entropy gain (more particles) drives chelate effect; overall formation constant is product of stepwise K
What each symbol means
| Symbol | What it stands for |
|---|---|
| \beta | Overall stability / formation constant |
When to use this
Ring formation 5- or 6-membered with metal is especially stable; ΔS > 0 main driver alongside ΔH.